Pollution source identification of nitrogen and phosphorus in the lower West Main Canal, the Ganfu Plain irrigation district (South China).

The degradation of surface water quality has been a widespread concern around the world. However, irrigation canal water does not attract much attention although it is important to agriculture and population. In this study, a 5-year water quality monitoring of surface water was conducted in the lower West Main Canal of the Ganfu Plain irrigation district to identify the levels and pollution sources of nitrogen and phosphorus.Over 75% of samples had total phosphorus (TP) concentrations of > 0.02 mg/L, and all samples had total nitrogen (TN) concentrations of > 0.2 mg/L, indicating a risk of eutrophication. The concentrations of NO3--N and NH4+-N averagely occupied 57% and 18% of TN, respectively. PCA analysis showed that phosphorus and nitrogen in canal water were associated with meteorological factors, urban life and surface runoff, agricultural cultivation, livestock-poultry breeding, and water-sediment interaction in the wet season, whereas they were affected by meteorological factors, industrial effluent, urban domestic sewage, and livestock-poultry breeding in the dry season. Absolute principal component score-multiple linear regression (APCS-MLR) model results revealed that (1) agricultural cultivation plus livestock-poultry breeding contributed 43.2% of TP in canal water in the wet season, while livestock-poultry breeding contributed 52.9% in the dry season, and (2) domestic sewage plus surface runoff contributed 29.4% of TN in the wet season, while livestock-poultry breeding contributed 45.9% in the dry season. The unidentified sources had significant contributions of > 20% for almost all variables. So further investigations are required for determining unidentified sources, and anthropogenic pollution control is imperative for canal water quality protection.

Chemical speciation of phosphorus in surface sediments from the Jiangsu Coast, East China: Influences, provenances and bioavailabilities.

Sixty-one surface sediment samples collected from the Jiangsu Coast (JSC), East China were investigated to explore the influences, provenances and bioavailabilities of P species. Authigenic and detrital P fractions were the dominant species, accounting for 28.53% and 44.04% of the total P content, respectively. Exchangeable, Fe-bound and organic P fractions were biologically available, with an average total of 5.94 µmol/g; this value was governed by grain sizes and the organic matter and carbonate contents. Exchangeable and organic P fractions were transformed between each other, while contributing to the formation of Fe-bound and authigenic P. Phosphorus in the JSC sediments originated mainly from the Yellow River. The unique distribution pattern of P species in the JSC depends on P sources and local environments. These findings improve our understanding of the P cycle and eutrophication in the Jiangsu Coastal Zone.

Phosphorus species in bottom sediments of the Three Gorges Reservoir during low and high water level periods.

Eutrophication and algal blooms have recently been found in the backwater areas of some tributaries in the Three Gorges Reservoir (TGR), for which phosphorus (P) is an important driving factor. However, P species in the TGR sediments at different water levels were little known. In this study, five P species of the TGR sediments during the high and low water level periods were analyzed with a sequential extraction method. The total P (TP) concentrations were 714.88 ± 37.86 µg/g and 697.57 ± 111.49 µg/g at the low and high water levels, respectively. The concentrations of P species decreased in the orders detrital P > authigenic P > organic P > iron-bound P > exchangeable P at the low water level and detrital P > organic P > authigenic P > iron-bound P > exchangeable P at the high water level. P in the TGR sediment sourced mainly from the upstream input at the low water level but from the inputs of tributaries and hillslope soils at the high water level. The bioavailable P (BAP) possessed > 29.5% of total P in the two periods. The total storages of total P and BAP were estimated to be about 1.34 × 106 t and 1.77 × 105 t, respectively during 2003-2017. It was further found that the BAP concentration significantly increased from periods I (2003-2009), II (2010-2014), to III (2015-2017), while the deposition flux and storage of BAP were the highest in period II. Our findings provide new insight into the P cycle and benefit eutrophication treatment in the TGR.